Abstract
Layered MCM-22(P) was synthesized in the presence of hexamethonium (HM) cations. Compared to zeolite EU-1 (EUO-type structure), which crystallizes in similar conditions, its formation is favored at high HM concentrations (HM/SiO2 ≥ 0.3) and in the absence of Na2O. HM-containing MCM-22(P) was used as starting material for zeolite formation. Upon hydrothermal treatment, HM-MCM-22(P) transforms into zeolite EU-1 and upon calcination into a MWW-type zeolite. Transformation mechanisms were studied by standard characterization techniques such as XRD, SEM and TEM. Catalytic properties of the MWW-type zeolite obtained from this precursor were evaluated in a m-xylene isomerization reaction. Compared to zeolite MCM-22 prepared with hexamethyleneimine, a higher catalytic activity and an increased isomerization selectivity were observed and discussed.
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