Abstract
Abstract β-(N,N-Dimethylcarbamoylselenenyl)- and β-(N,N-dimethylcarbamoyltellurenyl)alkenyl ketones were converted into isoselenazoles and isotellurazole Te-oxides, respectively, simply by treating with hydroxylamine-O-sulfonic acid, and deoxygenation of the latter products was successfully carried out by treating with PPh3. Alternative treatment of ynone oxime tosylates with hydrochalcogenide ions or N,N-dimethylchalcogenocarbamate ions also gave the same isochalcogenazole rings. These reactions were assumed to proceed through intramolecular nucleophilic substitution on the nitrogen atom of oxime sulfonates by the attack of in situ generated chalcogen nucleophiles.
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