Synthesis of Indium Oxide Octahedrons for Detection of Toxic Volatile Organic Vapors

Abstract

In <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> octahedronswere obtained using a simple freeze-dryingprocessfollowedby a calcination treatment. The morphology and chemical composition of the samples were investigated by field emission scanning electron microscopy (SEM), transmission electron microscopy, and X-ray diffraction (XRD). The In <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> sample had an octahedron shape, a smooth surface, high crystallinity, and a particle size of approximately 4 <inline-formula xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"> <tex-math notation="LaTeX">$\mu$ </tex-math></inline-formula> m. X-ray photoelectron spectroscopy (XPS) verified the existence of chemisorbed dissociated oxygen on the surface of the In <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> octahedrons, which has a meaningful impact on the sensing performance, leading to a high response. When used as a sensing material for volatile organic compounds (VOCs) detection, In <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> octahedrons exhibited superior sensing performance for isopropanol, ethanol, methanol, and acetone. The detection limits (LODs) of isopropanol and ethanol were 0.60 and 0.57 ppm (signal-to-noise ratio, S/N = 3), respectively. In addition, the In <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> octahedron sensor exhibited a short response, rapid recovery time, and good stability under long-term testing. The influence of the relative humidity (RH) on the In <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> octahedron sensor performance was also investigated. The outstanding sensing property of In <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> octahedrons was attributed to their high crystallinity and unique morphology.