Abstract
Wesentliche Elemente der Synthese von (−)-Hygromycin A sind die Aminohydroxylierung über einen Aminosubstituenten zur Bildung der Aminocyclitoleinheit und die Verwendung einer sperrigen Schutzgruppe an der Zuckereinheit, um die selektive Mitsunobu-Glycosylierung zu erleichtern und ein sonst empfindliches Proton kinetisch zu stabilisieren.
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