Synthesis of high surface area mesoporous ZnCl2–activated cocoa (Theobroma cacao L) leaves biochar derived via pyrolysis for crystal violet dye removal

Abstract

Chemically activated cocoa leaves biochar (CLB) was successfully prepared from fallen cocoa leaves (CLs) via ZnCl2–activation and pyrolysis at 700 °C for sequestration of toxic crystal violet (CV) dye from aqueous solution. CLs and CLB were characterized using elemental analysis (CHN/O), Brunauer-Emmett-Teller method (BET), thermogravimetric analysis (TGA), Fourier transform infrared (FTIR), X-ray diffraction (XRD) spectroscopy and scanning electron microscopy (SEM). The optimum conditions for effective removal of CV dye from aqueous solution (75.67% for CLs and 99.87% for CLB) were pH 9, initial CV dye concentration 100 mg/L, adsorbent (CLs/CLB) dose 0.4 g/L, contact time 160 min and temperature 300 K. Modified Ritchie second order best described kinetic and Liu model described equilibrium adsorption. CLs and CLB with maximum adsorption capacities 190.70 and 253.3 mg/g respectively, compete favorably with adsorbents used for removal of CV dye from wastewater in the literature. The high BET surface area (957.02 m2/g) and mean pore diameter (7.21 nm) were indicators of better adsorption efficiency of CLB. CLs showed adsorption to proceed towards endothermic process, while it was exothermic process for CLB. This study established the suitability of cocoa leaves as sustainable and environmental friendly precursor for preparation of adsorbent for the treatment of dye-containing wastewater.