Abstract
1. The interaction of NaGaH4 with 1-alkynes in the presence of secondary amines at 110–120° gave gallium acetylide complexes with a general formula NaGa(C≡CR)4, where R=C3H7, C4H9, C6H13, C6H5. 2. The reaction between NaGaH4 and secondary amines was studied, and compounds with the general formula NaGaHn(NR2)4−n, n=1,2 were obtained, where R=CH3, C2H5, C5H10. 3. The reaction between NaGaH4 and 1-alkynes in the presence of a secondary amine was shown to take place in a stepwise manner through the intermediate formation of amide derivatives of sodium gallohydride.
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