Abstract

Abstract 2, 3-Cyclohexene acetal, wherein the acetal wherein the acetal lunctionality is derived from 2R, 3R(+)-tartaric acid, has been transformed regioselectively into functionalised bicyclic α-methylene-γ-butyrolactoes via radical cyclisations. The radicals were derived from n-bu3SnH reactions with secondary bromides and a tertiary nitro compound.

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