Abstract
Transition-metal-catalyzed annulation reactions of difluorocyclopropenes with alkynes or N,N-dialkylformamides and homocoupling reaction of difluorocyclopropenes have been realized under mild conditions. These reactions tolerate a range of functional groups, furnishing the corresponding products in moderate to good yields. In addition, isotope labeling experiment shows that water indeed involves in these reactions as an important component.
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