Abstract
Abstract2,3,5,6,8,9‐Hexakis(bromomethyl)sumanene, a hexa‐substituted sumanene with bromomethyl groups at the peripheral aromatic carbons, was successfully synthesized in 97% yield with a one‐step reaction. Single‐crystal X‐ray structural analysis showed a formation of a dimer structure. The nucleophilic substitution afforded the introduction of several substituents. These UV‐vis absorption and emission spectra showed clear redshift compared with pristine sumanene, indicating the extension of the conjugation system of hexa‐substituted sumanenes.
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