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https://doi.org/10.1080/07328303.2011.642433
Copy DOIJournal: Journal of Carbohydrate Chemistry | Publication Date: Mar 1, 2012 |
Citations: 14 |
The fully O-benzylated pentasaccharide glycosyl azide representing the common core structure of N-glycans was synthesized. The β-mannosidic linkage was created by C-2 epimerization of the initially introduced β-d- gluco-unit via DMSO/Ac2O oxidation followed by stereoselective reduction with tetrabutylammonium borohydride.
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