Synthesis of Fluorine Analogs of Vitamin E. III. Synthesis of 2-(4,8-Dimethyl-12-(trifluoromethyl)tridecyl)-2,5,7,8-tetramethyl-6-chromanol and 2-(4,12-Dimethyl-8-(trifluoromethyl)tridecyl)-2,5,7,8-tetramethyl-6-chromanol.

Mayumi Koyama,Mihoko Tamura,Itsumaro Kumadaki,Akira Ando

doi:10.1248/cpb.42.2154

Synthesis of Fluorine Analogs of Vitamin E. III. Synthesis of 2-(4,8-Dimethyl-12-(trifluoromethyl)tridecyl)-2,5,7,8-tetramethyl-6-chromanol and 2-(4,12-Dimethyl-8-(trifluoromethyl)tridecyl)-2,5,7,8-tetramethyl-6-chromanol.

Mayumi Koyama, Mihoko Tamura + Show 2 more

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https://doi.org/10.1248/cpb.42.2154

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Journal: Chemical and Pharmaceutical Bulletin	Publication Date: Jan 1, 1994
Citations: 6	License type: free

Affiliation: Setsunan University

#Analogs Of Vitamin #Fluorine Analogs + Show 2 more

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Abstract

2-[4, 8-Dimethyl-12-(trifluoromethyl)tridecyl]-2, 5, 7, 8-tetramethyl-6-chromanol and 2-[4, 12-dimethyl-8-(trifluoromethyl)tridecyl]-2, 5, 7, 8-tetramethyl-6-chromanol, were synthesized by means of the Wittig reaction using the phosphonium salt of 2-(3-chloropropyl)-2, 5, 7, 8-tetramethyl-6-chromanol.

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