Synthesis of fibrous LaFeO3 perovskite oxide for adsorption of Rhodamine B

Abstract

The LaFeO3 perovskite oxide decorated active carbon fibers (LFO-ACFs) based on cotton fabric waste were successfully synthesized through sol-gel loading and thermal treatment. LaFeO3 perovskite and cotton fabric waste were combined to an eco-friendly and cheap adsorbent, which could reuse the leftover materials of textile industry and realize their functional modification. The structural, morphology/microstructure and functional groups were investigated through X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray (EDX), Fourier Transform Infrared spectroscopy (FTIR), respectively. The XRD pattern suggested the cotton fabric matrix didn’t influence the structure of LaFeO3 perovskite oxide. In SEM studies, LFO-ACFs still maintained fibrous shape of the raw cotton fibers, and the EDX analysis showed that the main elements of the prepared LFO-ACFs were La, Fe, O and C. The synthesized LFO-ACF was employed for adsorption of cational dye of Rhodamine B (RhB), and the effects of adsorption parameters, i.e. pH, contact time, solution temperature and initial concentration of dye, on adsorption behavior were investigated. Results suggested the adsorption performance of LFO-ACF for RhB was nearly not affected by solution pH and its maximum adsorption capacity fitted by the Langmuir isothermal model could attain 182.6 mg/g at 293 K. The adsorption kinetics followed the pseudo-second-order equation and the regeneration of LFO-ACF could be well realized through an easy pyrolysis method.