Abstract
A straightforward and effective method is reported for obtaining microtubes of iron‐based compounds by interfacial interaction between a solution and gaseous reagents. A thin amorphous film of Fe(OH)3 was synthesized on the surface of a mixed FeCl2/FeCl3/ascorbic acid aqueous solution as a result of the interaction with gaseous ammonium. When dried in air, the film was oxidized and transformed into microtubes. These Fe(OH)3 microtubes were converted into α‐Fe2O3 ones by annealing in air. As a result of thermal hydrogen reduction, α‐Fe microtubes were formed. Both the annealing in air and reduction in a hydrogen flow at a temperature of 1,000 °C preserve the tubular morphology of the product. The microtubes synthesized were characterized by optical and scanning microscopy, structural and compositional analyses, and Mössbauer spectroscopy. A hypothesis is proposed about the model of microtube formation resulting from the chemical reaction at the gas–solution interface.
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