Synthesis of Fe–Pr co-doped ZnO nanoparticles: Structural, optical and antibacterial properties

Abstract

In the present work, we studied the role of Fe and Pr addition on the structural, optical and antibacterial properties of spherical ZnO nanoparticles synthesized via sol gel method. The lattice constants values increased, while the average crystallite size decreases as the Pr concentration varies from 0.00 to 0.04. The Fe and Pr cations insertion in the Wurtzite structure were also confirmed by the changes in Zn–O bond length (1.9763 Å to 1.9793 Å for 0.00 ≤ y ≤ 0.04). Raman and FTIR spectroscopies validated the ZnO single-phase formation, and the analysis suggests the existence of oxygen vacancies. The samples showed agglomerated spherical morphology and formation of nanoplate homogeneously organized, while the textural properties were affected by the Fe inclusion. All samples presented band gap values lower than expected for bulk ZnO and the lowest values were obtained for samples containing Fe and Pr. The analysis and deconvolution of photoluminescence spectra confirmed the structural defects formation, caused by the synthesis conditions used and dopants ions inclusion. The antimicrobial activity against Escherichia coli and Staphylococcus aureus using the direct contact method showed superior activity for S. aureus due to the nanoparticles-bacteria interactions. The synergistic effect of dopants may have contributed to the better performance observed against S. aureus, while the Pr concentration directly influenced the inhibitory effect of E. coli. Therefore, the synthesized materials are promising to eliminate pathogenic microorganisms.