Abstract
Asymmetric transition-metal-catalyzed allylic substitutions are powerful synthetic transformations for the preparation of chiral allylic substrates. Herein, an iridium-catalyzed enantioselective allylation protocol using sodium thiophenoxide 1 as a nucleophile has been developed. The best selectivities could be achieved with the chiral monodentate phosphoramidite ligand L*(S,S,S a )-5 and CsF as an additive in dichloromethane.
Published Version
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