Abstract

Abstract An array of enantiomerically pure mononuclcear [Ru(bpy) 2 (dppz)] 2 + derivatives with 10,13-diaryl substituted dppz ligand has been synthesized and characterized (bpy = bipyridine, dppz = pyrido-[3,2-a:2′,3′-c]phenazine). These new complexes exhibit substantially similar absorption spectra, resembling the parent complex [Ru(bpy) 2 (dppz)] 2 + , and the enantiomerically pure analogues show the similar CD spectra in buffer solution despite the structural difference.

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