Abstract

The first synthesis of electrically conductive organic thin film by plasma polymerization (glow-discharge chemical vapour deposition) is reported. The monomer specifically employed is 3,4,9,10-perylenetracarboxylic dianhydride consisting of five-condensed aromatic rings attached by carboxylic groups outside the rings. The film is air-stable and hard enough not to be scratched out. Electrical conductivity of the samples measured is more than 1.0 × 10 0 S cm -1 with n-type carriers at room temperature. Preliminary spectroscopic data are also to be shown.

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