Abstract

Various lanthanum compounds were used as the catalyst for the synthesis of dimethyl carbonate (DMC) from methyl carbamate and methanol. Among them, La(NO 3) 3 presented the best catalytic performance with the DMC yield of 53.7% under suitable reaction conditions. Based on the results of X-ray diffraction, Fourier transform infrared spectroscopy and element analysis, a possible reaction mechanism over lanthanum nitrate was proposed for this reaction.

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