Abstract

Phenylene–thiophene oligomers bearing peracetylated β- d-glucose or N-BOC- l-phenylalanine as chiral substituents were synthesized in good yields by a versatile protocol based on the Suzuki–Miyaura cross-coupling reaction. Aryl iodides bearing the chiral biomolecules as substituents efficiently reacted with pinacol boronates of bi- or terthiophenes leading to the bio-functionalized oligomers in good yields.

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