Abstract
The review paper deals with catalytic systems based on porphyrin complexes of metals used for stimulation of reactions of olefins and carbon dioxide. It is shown that these porlhyrin complexes may behave as effective catalysts for carboxylation of epoxides. Specific features of catalysis of the interaction between oxiranes and carbon dioxide in the presence of homogeneous and heterogenized porphyrin complexes of metals, including those comprising various promoters, are considered.
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