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Abstract
The denticity of the thiolato ligand decides whether the cubane‐like cluster 1 or the bicubane‐like cluster 2 is obtained in the reaction of copper thiolates with the “butterfly” cluster [Cu2S3W(O)(PPh3)3]. This could also be confirmed by further cluster syntheses. Tungsten–copper–sulfur clusters such as 1 and 2 are of interest, inter alia, as models for the active centers of some enzymes. equation image
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