Synthesis of Copolymers of Decylmethacrylate with Decene-1 as a Viscosity Additive

Elkhan U Isakov,Jeyhun Sh Hamidova,Elnara I Hasanova

doi:10.4236/ojogas.2017.22006

Abstract

The article was dedicated to the copolymerization reaction of decylmethacrylate with decene-1. The copolymerizaion was realized with the participation of the inisiator the radical mechanism—izooil acid dinitrilyne. The learning of the polymerizaion reaction of decylmethacrylate with decene-1 shows that, it is possible to analyse the polymer connections having any molecular mass and content with the way of changing the monomers correlation and reaction temperature, that, it is possible to manage it knowing the regularities of the process. The effect of decylmethacrylate decene-1 copolymers to the viscosity-temperature properties has been learnt. As the result it has been showed that, using the joint polymers of decylmethacrylate—decene-1 in the content of the limpid oils as the thickener additive, it is possible to get the base oils with good viscosity-temperature properties.

Highlights

The used lubricating oils must be in high quality in order to ensure the longtime and reliable exploitation of the machine and mechanisms
The article was dedicated to the copolymerization reaction of decylmethacrylate with decene-1
The learning of the polymerizaion reaction of decylmethacrylate with decene-1 shows that, it is possible to analyse the polymer connections having any molecular mass and content with the way of changing the monomers correlation and reaction temperature, that, it is possible to manage it knowing the regularities of the process

Summary

Introduction

The used lubricating oils must be in high quality in order to ensure the longtime and reliable exploitation of the machine and mechanisms. Studying thermo destructive properties of the industrial oil I-12A with the addition of chemically modified olefins polyalkylmethacrylates and industrial type additives polyalkylmethacrylates (e.g., Viscoplex V-2-670) shows that viscosity decrease of the first is in the range of 3.0% - 6.0%, and for the second is 12.0% - 17.8%. This is connected with the formation of new chemical bonds in copolymers, and this connection is stronger than the bond straight chain polymers of C—C. As alkylmetarylate was taken decyl methacrylate, as α-olefin—decene-1

Exsperiments

Characteristics of the Copolymer of Decylmethacrylate— Decene-1

Results and Discussion

Conclusion