Abstract
The complexes Co3(CO)9(μ3-X) (X=S, Se) can be reduced to the corresponding anionic species [Co3(CO)9(μ3-X)]−, which react with allyl bromide to give Co3(CO)7(μ-η3-C3H5)(μ3-X) (X=S, Se). These are the first two cobalt complexes containing the bridging μ-η3-allyl ligand. The structure of the selenium complex was determined by X-ray crystallography. Crystal data for Co3(CO)7(μ-η3-C3H5)(μ3-Se) are as follows: space group P21/c, a=9.051(2) A, b=8.102(2) A, c=21.27(4) A, β=93.82(3)°, Z=4, and R=0.0565 for 2491 observed reflections.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.