Abstract

In the presence of a monovalent cobalt complex with EDMA, we sought to synthesize zeolite from aluminosilicate gels in hydrothermal conditions. Using these gels, we obtained three kinds of zeolites, i.e., of the MOR-, MFI-, and ANA-type. We characterized in detail the obtained MOR- and ANA-type zeolite by means of thermal analysis, UV–Vis-IR spectrometry and TOF-SIMS measurement. The results showed that cobalt atoms are located in the MOR- and ANA-type framework (namely through Co atom substitution), and not in the micropores as a complex. On the other hand, a small number of cobalt atoms are distributed in a micropore of the MFI-type zeolite as a cation.

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