Abstract

Cluster like mesoporous TiO2 spheres, nanorods and nanoparticles were synthesized by simple wet chemical method. The TiO2 mesoporous spheres, nanorods and nanoparticles were characterized by powder X-ray diffraction, Raman spectroscopy, ultraviolet visible spectroscopy, Fourier transform infrared spectroscopy, field emission scanning electron microscopy and transmission electron microscopy. Accordingly, a possible growth mechanism of mesoporous spheres, nanorods and nanoparticles were discussed. The changes of the dye-sensitized solar cell (DSSC) performance with the variation of the nanostructures of TiO2 which were used in photoanodes have been investigated. The TiO2 mesoporous sphere based DSSC with the film thickness of 20 μm was assembled and a conversion efficiency of 6.69% was obtained.

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