Abstract
Organic azides have been somewhat popularized due to their pivotal role in the emerging field of “click chemistry”. A simple approach has been used for the synthesis of uniform nano Fe‐MIL‐88B‐NH2, and a generic postsynthetic modification route has been developed for the synthesis of azide‐modified nano Fe‐MIL‐88B‐N3. The approach also has been used to synthesize the azide‐modified IRMOF‐3(‐N3). These new azide‐modified Fe‐MIL‐88B‐N3 nanocrystals hold promising potential for the applications in the fields of “click chemistry”, nanotechnology devices and nano composite membranes.
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