Synthesis of Citrate-Stabilized Silver Nanoparticles Modified by Thermal and pH Preconditioned Tannic Acid.

Rita La Spina,François Rossi,Margaret Holland,Douglas Gilliland,Fabiano Reniero,Dora Mehn,Francesco Fumagalli

doi:10.3390/nano10102031

Abstract

Silver nanoparticles (AgNPs) may be synthesized by many different methods, with those based on the thermal reduction of silver salts by citric acid or citric acid/tannic acid being amongst the most commonly used. These methods, although widely used and technically simple, can produce particles in which the size, polydispersivity and morphology can vary greatly. In this work nearly mono-dispersed spherical AgNPs have been synthesized via a one-step reduction method by using sodium citrate and varying quantities of Tannic Acid (TA), which was thermally conditioned prior to use in the growth process. It was found that the final size can be further tailored by controlling the amount of TA and the thermal conditioning of the TA at 60 °C at different time points, which changes the size and polydispersivity of AgNPs. To better understand the origin of this effect, optical spectroscopic analysis and 1H NMR of the TA following mild thermal conditioning of the solution have been done. Comparison of thermally conditioned TA and TA exposed to basic pH shows that similar chemical modifications occur and consequently produce similar effects on growth when used in the synthesis of AgNPs. It is proposed that thermal preconditioning of the TA introduces either chemical or structural changes, which decrease the final particle size under a given total silver content.

Highlights

Amongst the many types of nanomaterials currently in common use, silver nanoparticles (AgNPs) form one of the largest and fastest growing categories exploited in a wide variety of commercial and scientific applications
AgNPs were synthesized by varying the concentration of tannic acid (TA) in citrate solution (0, 3.3 × 10−7, 3.3 × 10−6 and 3.3 × 10−5 M)
The TA solution was mixed with the citrate solution and thermally preconditioned at 60 ◦C for 45 min prior to addition to a boiling solution of AgNO3

Summary

Introduction

Amongst the many types of nanomaterials currently in common use, silver nanoparticles (AgNPs) form one of the largest and fastest growing categories exploited in a wide variety of commercial and scientific applications. Depending on the actual size required, the methods of synthesising water-dispersible AgNPs, which are probably the simplest and most commonly adopted, are based on the reduction of silver salts in the presence of sodium citrate as a principal stabiliser/reducing agent [5]. Such methods, widely used and desirable because of their low cost, simplicity and low toxicity, are not always suitable as they may require careful optimisation to avoid broad size distributions and mixtures of different morphologies

Methods

Results

Conclusion