Abstract

We report a facile two step synthesis of chiral ligands for bonding to transition metals. The ligands are easily prepared from trans-1,2-diaminocyclohexane by reaction with sulfonyl chlorides to give amino-sulfonamide compounds. These intermediates are then condensed with salicylaldehyde derivatives to provide sulfonamide/Schiff base compounds which represent a new class of chiral ligands.

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