Abstract
[reaction: see text] Treatment of the benzannulated enediyne 11 with potassium tert-butoxide in refluxing toluene for 12 h produced 15 via a cascade sequence of cyclization reactions. Two subsequent palladium-catalyzed intramolecular arylation reactions then afforded the bowl-shaped polycyclic aromatic hydrocarbon 16. The X-ray structures of 16 and two closely related molecules show the presence of significant curvatures.
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