Abstract
AbstractBis(catechol) ligands derived from 2,8‐disubstituted analogues of Tröger's base and monofunctionalized MOM‐protected or unprotected catechols bearing both rigid and flexible spacers were synthesized, which gave rise to dissymmetric oxygen donor ligands whose geometry is defined by the V‐shaped and rigid structure of the core of Tröger's base. These racemic ligands undergo self‐assembly to dinuclear triple‐stranded helicates upon coordination to titanium(IV) ions as was proven by NMR spectroscopy and ESI‐MS experiments; however, these processes are not diastereoselective.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
