Abstract
The cross-coupling reaction of tolylboronic acids (1.3 equiv.) with chloroarenes in toluene was carried out at 80–100°C in the presence of a NiCl 2/PPh 3 catalyst (3 mol%) and K 3PO 4· nH 2O (2.6 equiv.). The reaction can be applied to various electron-deficient and -rich chloroarenes and is economical as the industrial process.
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