Abstract

AbstractPolyaromatic organic compounds have attracted significant attention because of their wide range of applications in various functional materials. Recently, transition-metal-catalyzed C–H bond activation and the subsequent oxidative cyclization with unsaturated compounds has emerged as a promising synthetic method for multiring systems. We report a two-step synthesis of binaphthyl-fused chiral bibenzo[g]coumarin derivatives by Rh-catalyzed annulative coupling reaction of BINOL-based thiocarbamates with alkynes. The optical properties of the coupling products were evaluated.

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