Abstract
One methyl-tin bond was selectively cleaved from aryltrimethyltin compounds by sodium metal in liquid ammonia. The triorganyl-stannyl anions thus obtained are arylated by chloroarenes by means of photostimulated S RN1 reactions. Such reactions can be repeated to replace all methyl groups by different aryl groups. The one-pot synthesis of asymmetric triarylmethyltin compounds can be achieved from trimethyltin chloride.
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