Abstract
A new class of pyrrole derivatives containing methyl benzoate groups, MB3PE2 and MB3, were synthesized using the Sonogashira coupling reaction, and were used to develop typical donor (D, pyrrole)-acceptor (A, -PhCOOCH3) fluorophores that exhibited tunable fluorescent properties. Moreover, their emission properties and fluorescence dynamics were systematically investigated to elucidate their structure-property relationships. The results revealed that the π-conjugation and/or D-A geometry of these compounds has a significant effect on their emissive behaviors. MB3PE2 has π-T-shaped D-A structure while MB3 has T-shaped D-A structure. Both of them emit blue light with apparent solvatochromic effects but had different quantum yields in different states such as solution and aggregates states, which are more 2.6 times quantum yield of π-T-shaped D-A MB3PE2 than that of T-shaped MB3.The result provides a guidance for designing new D-A dyes with high quantum yield in solution.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
