Abstract
The nuclear–chemical method has been used for the synthesis of previously unknown multivalent fluorine derivatives, namely (4-methylphenyl)phenylfluoronium. The synthesis includes the ion-molecular reaction of free phenyl cations generated by tritium β-decay with 4-methylhalobenzenes. The influence of the halogen atom (F, Cl, Br, I) as well as effects of the methyl substituent on the yields of the corresponding halonium compounds have been investigated.
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