Abstract
AbstractHerein, a simple and useful approach to angular triquinane and [4.3.3]propellane moieties is described via olefin metathesis starting from exo and endo Diels‐Alder (DA) adducts containing norbornene unit. This approach involves DA reaction, and ring‐rearrangement metathesis (RRM) as key steps. Strained norbornene derivatives on allylation at bridgehead position(s) followed by ring‐opening metathesis and ring‐closing metathesis sequence delivered angular triquinane and also stereochemically different propellane derivatives.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.