Abstract
A series of β-alkyl-α,β-unsaturated trifluoromethyl ketones have been prepared from the corresponding α-acetylenic trifluoromethyl ketones. The addition of sulfur nucleophiles was shown by chemical and 19 F NMR studies to proceed exclusively by 1,4-addition with no indication of any 1,2-addition products. The unsaturated trifluoromethyl ketones have been shown to be effective inhibitors of rat cytosolic glutathione-S-transferase
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