Abstract
Micellar catalysis has been used to synthesis a sugar-amino acid based cationic surfactant (N,N,N-trimethyl-2-oxo-2-(((2R,3S,4S,5R)-3,4,5-trihydroxy-6-(tetradecyloxy)tetrahydro-2H-pyran-2-yl)methoxy)ethan-1-aminium iodide) with renewable raw materials in aqueous media. The micellar catalysis method was compared with the method that uses dimethylformamide (DMF) as solvent. The results confirm the superiority of micellar catalysis method in terms of efficiency, energy consumption and environmental issues. Common physicochemical properties of surfactants like critical micelle concentration (CMC), the minimum surface area per molecule (Amin) and Krafft temperature were determined to evaluate the behavior of synthesized surfactant properties at the air-water interface. Computational chemistry method (DFT (B3LYP/6-311g(d)) was conducted to calculate the dimensional properties of the surfactant to determine the shape, size and aggregation number of micelles at their CMC by an approach that uses Connolly solvent accessible area as the effective area of surfactant head groups. Dynamic light scattering method (DLS) was used to determine the size of micelles. The results of DLS tests show good agreement with the calculation method. Finally, the biodegradability of synthesized natural based cationic surfactant was studied by close bottle standard test to investigate the biodegradation of synthesized surfactant.
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