Abstract

We report on the design, optimized synthesis, and characterization of a thiophene–phthalimide based small molecule. We show that microwave irradiation is a useful technique to accelerate direct arylation cross-coupling reactions, and that the thiophene–phthalimide architecture can lead to face-to-face intermolecular π-stacking, resulting in pronounced blue shifts in the absorption maximum upon a solution to condensed state transition.

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