Abstract
Amphiphilic meso-aryl-substituted porphyrins containing an amino group and long-chain hydrophobic substituents were synthesized. Two strategies of the synthesis of asymmetric amino-containing porphyrins using p-acetamidobenzaldehyde and p-nitrobenzaldehyde were developed and investigated. A series of new substituted porphyrin-containing closo-decaborates were prepared based on the synthesized porphyrins and nitrilium derivatives of the closo-decaborate anion [B10H10]2−.
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