Synthesis of AgNPs from waste mobile phone circuit boards using an emulsion liquid membrane method

Abstract

The disposal of mobile phone print circuit boards (WMPCBs) has now been a problem because of the continually increasing production of mobile phones. It could be considered a new source of precious metal but may jeopardize the environment and human health without proper management. An emulsion liquid membrane (ELM) method is applied and improved to recover silver from WMPCBs and prepare AgNPs. The effects of significant operating parameters were studied for a better understanding of the ELM process. Under the optimized conditions i.e., 0.25 % (v/v) Cyanex 302, 6 % (v/v) Span 80, 5 % (w/v) ASC, 3500 rpm emulsification speed, 10 min emulsification time, 300 rpm extraction stirring speed, 10 min extraction stirring time and 3 (v/v) phase ratio, 98.7 % silver was extracted. AgNPs produced were flower structures assembled by a group of individual nanosheets with a diameter of 800–1400 nm and a thickness of 10–14 nm. The purity was 98.7 % and the yield was 96.6 %. AgNPs of oblate spheroidal structure with a diameter of 30–50 nm could be synthesized by controlling the concentration of Span 80 in ELM. The current study intends to fulfill the gap by exploring the recovery of silver from WMPCBs by the ELM method.