Synthesis of Ag/g‐C3N4 Composite as Highly Efficient Visible‐Light Photocatalyst for Oxidative Amidation of Aromatic Aldehydes

Abstract

AbstractIn this contribution, an Ag/g‐C3N4 nanocomposite was synthesized and utilized as highly efficient and green photocatalyst for organic reactions under visible light irradiation. A layered, porous g‐C3N4 was synthesized following a modified solvothermal‐roasting process by using melamine and cyanuric chloride as precursor. Silver nanoparticles (NPs) were well anchored on g‐C3N4 nanosheets, which were prepared by a facile impregnation–roasting method. The inexpensive, stable g‐C3N4 coupled with the localized surface plasmon resonance (LSPR) effect of Ag NPs exhibited high photocatalytic activities toward aerobic oxidative amidation of aromatic aldehydes under visible light irradiation. Good to excellent yields were achieved for various substrates under the light of a 25 W compact fluorescent light (CFL) bulb in air. The operationally easy procedure provides an economical, green, and mild alternative for the formation of amide bonds.magnified image