Abstract

Syntheses of two [Ir(bipy)(Ppy)2] complexes functionalized with mannose and galactose are reported. The complexes were characterized by NMR and mass spectrometry. Fluorescence studies have shown enhanced interaction of the mannose-functionalized complex with mannose specific lectin concanavalin A whereas the galactose-functionalized complex did not show any interaction. The binding constant (2.9×105mol−1) was determined from the fluorescence spectroscopic data.

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