Abstract
A novel host inclusion complex of cross-linking-polymeric-β-cyclodextrin- o-vanillin furfuralhydrazone (β-CDP-OVFH) was synthesized and characterized with IR and 1H NMR spectra to confirm its structure. The coordination reaction of the host reagent with Cd 2+ was studied and the optimum reacting conditions were observed carefully. A highly selective and sensitive spectrofluorimetric determination of trace amount of cadmium was proposed based on the reaction of Cd 2+ with β-CDP-OVFH in ammonia water–ammonium acetate buffer medium of pH=11.0. The molar ratio of β-CDP-OVFH to Cd 2+ was 1:1. The maximum excitation and emission wavelengths were 393 and 494 nm, respectively. The linear range of this method was from 3.0 to 500 μg l −1 with a detection limit of 0.80 μg l −1. The effect of interferences in the determination of cadmium was investigated and the results showed that the host reagent had quite high capacity of identifying Cd 2+. The proposed method was successfully applied to the determination of trace amount of Cd 2+ in mussel and tea samples.
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