Synthesis of a novel copper(II) complex and its crystal structure

Abstract

One novel chiral copper(II) complex was successfully synthesized from the reaction of chiral 1,3-thiazolidine-2-thione ligand with CuCl 2 in dichloromethane in the presence of Et 3N and DMAP at room temperature. Its unique crystal structure was unambiguously disclosed by X-ray analysis. The crystal is tetragonal, space group I4(1), space group a=15.0875(11), b=15.0875(11), c=19.362(3) Å, α=90, β=90, γ=90°, V=4407.4(8) Å 3, Z=8, ρ calc=1.639 mg cm −3.