Abstract
AbstractTreatment of complex [Cp*Fe(μ‐SEt)3FeCp*] (1; Cp* = pentamethylcyclopentadienyl) with isocyanides CNR affords the mononuclear complexes [Cp*FeSEt(CNR)2] (2a, R = tBu; 2b, R = Ph; 2c, R = Cy; 2d, R = Bn) in moderate yield. The heterobinuclear complexes [Cp*FeCNR(μ‐CNR)(μ‐SEt)PdCl(PPh3)][PF6] (3a, R = tBu; 3b, R = Ph; 3c, R = Cy; 3d, R = Bn), [Cp*Fe(CNtBu)2(μ‐SEt)NiCl(PPh3)][PF6] (4), and heterotrinuclear complexes [{Cp*Fe(CNtBu)2(μ‐SEt)}2M][PF6] (5, M = Au; 6, M = Ag; 7, M = Cu) have been prepared by the reaction of 2 with complexes [PdCl2(PPh3)2], [NiCl2(PPh3)2], and [(Ph3P)M][X] (X = PF6 or OTf, OTf = OSO2CF3), respectively. These complexes have been spectroscopically and crystallographically characterized.
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