Abstract
Complexation of a CuI ion in a mercuramacrocycle demonstrates the potential of metal–metal interactions in a preorganized system to trap metal ions. The molecular structure of the CuI complex is presented and shows Hg⋅⋅⋅Cu heterometallic and Hg⋅⋅⋅Hg homometallic d10⋅⋅⋅d10 interactions (see figure).
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