Abstract
In this study, a clustered carbon aerogel interconnected by carbon balls (CCAI-CB) was prepared as an electrode material to construct a multi-functional electrochemical sensor. CCAI-CB derived from taros (Colocasia esculenta (L). Schott) possesses meso-macroporous structure and plenty of defective sites, and shows notable activity in electrocatalysis as an electrode material. We investigated the application of CCAI-CB modified glassy carbon electrode (CCAI-CB/GCE) for determination of ascorbic acid (AA) and hydrogen peroxide (H2O2). Compared with carbon nanotubes (CNTs) modified GCE (CNTs/GCE) and bare GCE, CCAI-CB/GCE shows lower detection limit (0.23 μM for AA and 1.31 μM, S/N = 3), higher sensitivities (220.53, 148.86 or 94.39 μA mM−1 cm−2 for AA and 83.06 or 49.07 μA mM−1 cm−2 for H2O2). Concentrations of AA and H2O2 in real samples were determined at CCAI-CB/GCE with satisfactory detection results obtained. In addition, when the CCAI-CB/GCE was used for electrocatalysis of other biomolecules, it also exhibits high electrochemical activity. Thus, CCAI-CB could be a promising electrode material for the construction of multi-functional electrochemical sensors.
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