Abstract

Methodology for the synthesis of 9, 10-dihydrophenanthrene, alkyl phenanthrene and Octahydro-phenanthrene has been developed via a palladium- catalyzed Heck reaction followed by Reverse Diels-Alder reaction of formaldehyde elimination. Reported methods are useful for the synthesis of higher homologous of polynuclear aromatic hydrocarbons.

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