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Abstract
Reaction of vinyl acetate with tricyclo[5.2.12.5.1.02.6]deca-3,8-diene in the presence of nano-TiO2 (20 nm) catalyst was studied. 8-Acetoxytetracyclo[4.4.12.5.17.10.01.6]dodec-3-ene was obtained in 88.5% yield. Addition of saturated monobasic acids C1-C5 to the obtained unsaturated monoester in the presence of the boron trifluoride etherate catalyst was investigated. Corresponding diesters were obtained in 68.1–93.0% yield. They can be used as the additives to synthetic oils and as components of perfumes.
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